Preprints
https://doi.org/10.5194/ar-2026-16
https://doi.org/10.5194/ar-2026-16
22 Apr 2026
 | 22 Apr 2026
Status: this preprint is currently under review for the journal AR.

Continuous new particle formation in a Mediterranean coastal environment: Insights from atmospheric ions behaviour analysis

Nikos Kalivitis, Spyridon-Emmanouil Markoulakis, Panayiotis Kalkavouras, Veli-Matti Kerminen, Markku T. Kulmala, and Maria Kanakidou

Abstract. Atmospheric new particle formation (NPF) is crucial for aerosol number concentration and for studying the production processes of secondary aerosol particles. NPF events are commonly classified based on visible particle growth, and their occurrence frequency is often underestimated. Recent methodologies propose that "quiet" NPF (QNPF) events, which are not traditionally classified as NPF events, can contribute significantly to particle number concentrations. This study presents three-years (June 2020–May 2023) of observations of ion and particle size distributions performed at the Finokalia environmental research station in Crete, Greece, using a Neutral cluster and Air Ion Spectrometer (NAIS) and a Mobility Particle Size Spectrometer (MPSS). By analysing the observed ion number size distributions and applying a nanoparticle ranking analysis method, this study reveals that QNPF events are frequent and contribute significantly to particle formation and growth in the Eastern Mediterranean. Negatively charged intermediate size ions are found to be reliable indicators of particle formation, including both classical NPF and QNPF episodes. Our analysis indicates continuous particle formation even on days traditionally classified as "non-event" days, providing fundamentally new understanding of NPF processes in the region.

Competing interests: At least one of the (co-)authors is a member of the editorial board of Aerosol Research.

Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this paper. While Copernicus Publications makes every effort to include appropriate place names, the final responsibility lies with the authors. Views expressed in the text are those of the authors and do not necessarily reflect the views of the publisher.
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Nikos Kalivitis, Spyridon-Emmanouil Markoulakis, Panayiotis Kalkavouras, Veli-Matti Kerminen, Markku T. Kulmala, and Maria Kanakidou

Status: open (until 03 Jun 2026)

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Nikos Kalivitis, Spyridon-Emmanouil Markoulakis, Panayiotis Kalkavouras, Veli-Matti Kerminen, Markku T. Kulmala, and Maria Kanakidou
Nikos Kalivitis, Spyridon-Emmanouil Markoulakis, Panayiotis Kalkavouras, Veli-Matti Kerminen, Markku T. Kulmala, and Maria Kanakidou
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Short summary
Atmospheric new particle formation (NPF) is crucial for aerosol number concentration. Recent methodologies propose that “quiet” NPF (QNPF) events, which are not traditionally classified as NPF, can contribute significantly to aerosol number. This study presents three-years of observations of ion and particle size distributions at the Finokalia station in Eastern Mediterranean. It shows that QNPF events are frequent providing fundamentally new understanding of NPF processes in the region.
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