Aerosol Research
Aerosol Research
Aerosol Research
Articles | Volume 3, issue 2
Articles | Volume 3, issue 2
https://doi.org/10.5194/ar-3-417-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/ar-3-417-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 3, issue 2
Research article
 | 
04 Jul 2025
Research article |  | 04 Jul 2025

A theory-informed, experiment-based constraint on the rate of autoxidation chemistry – an analytical approach

Lukas Pichelstorfer, Simon P. O'Meara, and Gordon McFiggans

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Latest update: 25 May 2026
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Short summary
Quantification of autoxidation chemistry is a complex task essential to our understanding of atmospheric secondary aerosol formation and its impact on climate. In this work, we introduce the autoCONSTRAINT module, a semi-empirical method for deducing reaction rate coefficients for lumped autoxidation chemistry schemes based on experimental data. The theoretical approach is analytical and provides mathematically correct though non-unique solutions with low computational cost.
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