Articles | Volume 3, issue 1
https://doi.org/10.5194/ar-3-101-2025
https://doi.org/10.5194/ar-3-101-2025
Research article
 | 
27 Feb 2025
Research article |  | 27 Feb 2025

Base synergy in freshly nucleated particles

Galib Hasan, Haide Wu, Yosef Knattrup, and Jonas Elm

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Stability and composition of large sulfuric acid–methanesulfonic acid–base molecular clusters
Galib Hasan, Yosef Knattrup, Haide Wu, and Jonas Elm
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Cited articles

Alfaouri, D., Passananti, M., Zanca, T., Ahonen, L., Kangasluoma, J., Kubečka, J., Myllys, N., and Vehkamäki, H.: A study on the fragmentation of sulfuric acid and dimethylamine clusters inside an atmospheric pressure interface time-of-flight mass spectrometer, Atmos. Meas. Tech., 15, 11–19, https://doi.org/10.5194/amt-15-11-2022, 2022. a
Almeida, J., Schobesberger, S., Kürten, A., et al.: Molecular Understanding of Sulphuric Acid-Amine Particle Nucleation in the Atmosphere, Nature, 502, 359–363, https://doi.org/10.1038/nature12663, 2013. a, b, c, d
Bannwarth, C., Caldeweyher, E., Ehlert, S., Hansen, A., Pracht, P., Seibert, J., Spicher, S., and Grimme, S.: Extended tight-binding quantum chemistry methods, WIREs Comput. Mol. Sci., 11, e1493, https://doi.org/10.1002/wcms.1493, 2021. a
Besel, V., Kubecka, J., Kurten, T., and Vehkamaki, H.: Impact of quantum chemistry parameter choices and cluster distribution model settings on modeled atmospheric particle formation rates, J. Phys. Chem. A, 124, 5931–5943, 2020. a
Bianchi, F., Tröstl, J., Junninen, H., Frege, C., Henne, S., Hoyle, C. R., Molteni, U., Herrmann, E., Adamov, A., Bukowiecki, N., Chen, X., Duplissy, J., Gysel, M., Hutterli, M., Kangasluoma, J., Kontkanen, J., Kürten, A., Manninen, H. E., Münch, S., Peräkylä, O., Petäjä, T., Rondo, L., Williamson, C., Weingartner, E., Curtius, J., Worsnop, D. R., Kulmala, M., Dommen, J., and Baltensperger, U.: New particle formation in the free troposphere: A question of chemistry and timing, Science, 352, 1109–1112, https://doi.org/10.1126/science.aad5456, 2016. a
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Aerosol formation is an important process for our global climate. However, there are high uncertainties associated with the formation of new aerosol particles. We present quantum chemical calculations of large atmospheric molecular clusters composed of sulfuric acid (SA), ammonia (AM), and dimethylamine (DMA). We find that mixed SA–AM–DMA systems cluster more efficiently for freshly nucleated particles compared to pure SA–AM and SA–DMA systems.
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