Articles | Volume 2, issue 2
https://doi.org/10.5194/ar-2-235-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/ar-2-235-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
22 Jul 2024
Research article |
| 22 Jul 2024
| 22 Jul 2024
Vertical concentrations gradients and transport of airborne microplastics in wind tunnel experiments
Eike Maximilian Esders
CORRESPONDING AUTHOR
Micrometeorology Group, University of Bayreuth, Universitätsstraße 30, Bayreuth, Germany
Christoph Georgi
Institute of Environmental Technology, Technische Universität Berlin, Straße des 17. Juni 135, Berlin, Germany
Wolfgang Babel
Micrometeorology Group, University of Bayreuth, Universitätsstraße 30, Bayreuth, Germany
Bayreuth Center of Ecology and Environmental Research, Dr.-Hans-Frisch-Str.1-3, Bayreuth, Germany
Andreas Held
Institute of Environmental Technology, Technische Universität Berlin, Straße des 17. Juni 135, Berlin, Germany
Christoph Karl Thomas
Micrometeorology Group, University of Bayreuth, Universitätsstraße 30, Bayreuth, Germany
Bayreuth Center of Ecology and Environmental Research, Dr.-Hans-Frisch-Str.1-3, Bayreuth, Germany
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Atmos. Chem. Phys., 18, 8249–8264, https://doi.org/10.5194/acp-18-8249-2018, https://doi.org/10.5194/acp-18-8249-2018, 2018
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Kathrin Gatzsche, Wolfgang Babel, Eva Falge, Rex David Pyles, Kyaw Tha Paw U, Armin Raabe, and Thomas Foken
Biogeosciences, 15, 2945–2960, https://doi.org/10.5194/bg-15-2945-2018, https://doi.org/10.5194/bg-15-2945-2018, 2018
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The ecosystem is a significant sink of carbon dioxide. To quantify this sink, very complex and validated models are required. However, the comparison of modeled and measured energy and matter fluxes in a heterogeneous landscape is still a challenge. On the one hand, models must be applied for various surface types, while on the other hand the comparison of the fluxes is only possible based on the flux source areas. This paper treats the potential aggregation of modeled fluxes and its validation.
Armin Sigmund, Lena Pfister, Chadi Sayde, and Christoph K. Thomas
Atmos. Meas. Tech., 10, 2149–2162, https://doi.org/10.5194/amt-10-2149-2017, https://doi.org/10.5194/amt-10-2149-2017, 2017
Martin Brüggemann, Laurent Poulain, Andreas Held, Torsten Stelzer, Christoph Zuth, Stefanie Richters, Anke Mutzel, Dominik van Pinxteren, Yoshiteru Iinuma, Sarmite Katkevica, René Rabe, Hartmut Herrmann, and Thorsten Hoffmann
Atmos. Chem. Phys., 17, 1453–1469, https://doi.org/10.5194/acp-17-1453-2017, https://doi.org/10.5194/acp-17-1453-2017, 2017
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Using complementary mass spectrometric techniques during a field study in central Europe, characteristic contributors to the organic aerosol mass were identified. Besides common marker compounds for biogenic secondary organic aerosol, highly oxidized sulfur species were detected in the particle phase. High-time-resolution measurements revealed correlations between these organosulfates and particulate sulfate as well as gas-phase peroxyradicals, giving hints to underlying formation mechanisms.
Shang Sun, Alexander Moravek, Lisa von der Heyden, Andreas Held, Matthias Sörgel, and Jürgen Kesselmeier
Atmos. Meas. Tech., 9, 599–617, https://doi.org/10.5194/amt-9-599-2016, https://doi.org/10.5194/amt-9-599-2016, 2016
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We present a dynamic twin-cuvette system for quantifying the trace gas exchange fluxes between plants and the atmosphere under controlled temperature, light, and humidity conditions. We found out that at a relative humidity of 40 %, the deposition velocity ratio of O3 and PAN was determined to be 0.45. At that humidity, the O3-deposition to the plant leaves was found to be only controlled by leaf stomata. For PAN, an additional resistance inhibited the uptake of PAN by the leaves.
M. Sörgel, I. Trebs, D. Wu, and A. Held
Atmos. Chem. Phys., 15, 9237–9251, https://doi.org/10.5194/acp-15-9237-2015, https://doi.org/10.5194/acp-15-9237-2015, 2015
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D. Plake, M. Sörgel, P. Stella, A. Held, and I. Trebs
Biogeosciences, 12, 945–959, https://doi.org/10.5194/bg-12-945-2015, https://doi.org/10.5194/bg-12-945-2015, 2015
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Grasslands cover vast terrestrial areas and the main biomass is concentrated in the lowest part of the canopy. We found that measured transport times in the lowermost canopy layer are fastest during nighttime. During daytime, the reaction of NO with O3, as well as NO2 uptake by plants, was faster than transport. This suggests that grassland canopies of similar structure may exhibit a strong potential to retain soil emitted NO due to oxidation and subsequent uptake of NO2 by plants.
W. Babel, T. Biermann, H. Coners, E. Falge, E. Seeber, J. Ingrisch, P.-M. Schleuß, T. Gerken, J. Leonbacher, T. Leipold, S. Willinghöfer, K. Schützenmeister, O. Shibistova, L. Becker, S. Hafner, S. Spielvogel, X. Li, X. Xu, Y. Sun, L. Zhang, Y. Yang, Y. Ma, K. Wesche, H.-F. Graf, C. Leuschner, G. Guggenberger, Y. Kuzyakov, G. Miehe, and T. Foken
Biogeosciences, 11, 6633–6656, https://doi.org/10.5194/bg-11-6633-2014, https://doi.org/10.5194/bg-11-6633-2014, 2014
S. G. Gonser, F. Klein, W. Birmili, J. Größ, M. Kulmala, H. E. Manninen, A. Wiedensohler, and A. Held
Atmos. Chem. Phys., 14, 10547–10563, https://doi.org/10.5194/acp-14-10547-2014, https://doi.org/10.5194/acp-14-10547-2014, 2014
M. Tjernström, C. Leck, C. E. Birch, J. W. Bottenheim, B. J. Brooks, I. M. Brooks, L. Bäcklin, R. Y.-W. Chang, G. de Leeuw, L. Di Liberto, S. de la Rosa, E. Granath, M. Graus, A. Hansel, J. Heintzenberg, A. Held, A. Hind, P. Johnston, J. Knulst, M. Martin, P. A. Matrai, T. Mauritsen, M. Müller, S. J. Norris, M. V. Orellana, D. A. Orsini, J. Paatero, P. O. G. Persson, Q. Gao, C. Rauschenberg, Z. Ristovski, J. Sedlar, M. D. Shupe, B. Sierau, A. Sirevaag, S. Sjogren, O. Stetzer, E. Swietlicki, M. Szczodrak, P. Vaattovaara, N. Wahlberg, M. Westberg, and C. R. Wheeler
Atmos. Chem. Phys., 14, 2823–2869, https://doi.org/10.5194/acp-14-2823-2014, https://doi.org/10.5194/acp-14-2823-2014, 2014
N. Niedermeier, A. Held, T. Müller, B. Heinold, K. Schepanski, I. Tegen, K. Kandler, M. Ebert, S. Weinbruch, K. Read, J. Lee, K. W. Fomba, K. Müller, H. Herrmann, and A. Wiedensohler
Atmos. Chem. Phys., 14, 2245–2266, https://doi.org/10.5194/acp-14-2245-2014, https://doi.org/10.5194/acp-14-2245-2014, 2014
K. A. Kamilli, L. Poulain, A. Held, A. Nowak, W. Birmili, and A. Wiedensohler
Atmos. Chem. Phys., 14, 737–749, https://doi.org/10.5194/acp-14-737-2014, https://doi.org/10.5194/acp-14-737-2014, 2014
S. G. Gonser and A. Held
Atmos. Meas. Tech., 6, 2339–2348, https://doi.org/10.5194/amt-6-2339-2013, https://doi.org/10.5194/amt-6-2339-2013, 2013
M. Li, W. Babel, K. Tanaka, and T. Foken
Atmos. Meas. Tech., 6, 221–229, https://doi.org/10.5194/amt-6-221-2013, https://doi.org/10.5194/amt-6-221-2013, 2013
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Aerosol formation is an important process for our global climate. However, there are high uncertainties associated with the formation of new aerosol particles. We present quantum chemical calculations of large atmospheric molecular clusters composed of sulfuric acid (SA), ammonia (AM), and dimethylamine (DMA). We find that mixed SA–AM–DMA systems cluster more efficiently for freshly nucleated particles compared to pure SA–AM and SA–DMA systems.
Ida Karppinen, Dominika Pasik, Emelda Ahongshangbam, and Nanna Myllys
Aerosol Research Discuss., https://doi.org/10.5194/ar-2024-38, https://doi.org/10.5194/ar-2024-38, 2025
Revised manuscript accepted for AR
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Acyl peroxy radicals can act as atmospheric oxidants of unsaturated hydrocarbons if their 1) unimolecular reactions are slow and 2) bimolecular accretion reactions are fast. Using theoretical tools, we show which acyl peroxy radicals should be considered as oxidants in the atmosphere.
Haide Wu, Yosef Knattrup, Andreas Buchgraitz Jensen, and Jonas Elm
Aerosol Research, 2, 303–314, https://doi.org/10.5194/ar-2-303-2024, https://doi.org/10.5194/ar-2-303-2024, 2024
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The exact point at which a given assembly of molecules represents an atmospheric molecular cluster or a particle remains ambiguous. Using quantum chemical methods, here we explore a cluster-to-particle transition point. Based on our results, we deduce a property-based criterion for defining freshly nucleated particles (FNPs) that act as a boundary between discrete cluster configurations and bulk particles.
Anindya Ganguly, Khaled Mosharraf Mukut, Somesh Roy, Georgios Kelesidis, and Eirini Goudeli
Aerosol Research Discuss., https://doi.org/10.5194/ar-2024-34, https://doi.org/10.5194/ar-2024-34, 2024
Revised manuscript accepted for AR
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The study explores the formation of small soot clusters by precursor molecules at high temperature. Higher temperature speeds up the decomposition of gas molecules, accelerating the formation of cyclic structures decorated by aliphatic chains. This research offers new insights into the early steps of soot formation, which could help develop more informed kinetic models for pyrolysis and combustion processes.
Astrid Nørskov Pedersen, Yosef Knattrup, and Jonas Elm
Aerosol Research, 2, 123–134, https://doi.org/10.5194/ar-2-123-2024, https://doi.org/10.5194/ar-2-123-2024, 2024
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Aerosol formation is an important process for our global climate. While inorganic species have been shown to be important for aerosol formation, there remains a large gap in our knowledge about the exact involvement of organics. We present a new quantum chemical procedure for screening relevant organics that for the first time allows us to obtain direct molecular-level insight into the organics involved in aerosol formation.
Marie K. Mikkelsen, Jesper B. Liisberg, Maarten M. J. W. van Herpen, Kurt V. Mikkelsen, and Matthew S. Johnson
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Short summary
Short summary
We analyze the mechanism whereby sunlight and iron catalyze the production of chlorine from chloride in sea spray aerosol. This process occurs naturally over the North Atlantic and is the single most important source of chlorine. We investigate the mechanism using quantum chemistry, laboratory experiments, and aqueous chemistry modelling. The process will change depending on competing ions, light distribution, acidity, and chloride concentration.
Cited articles
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Short summary
Our study explores how tiny plastic particles, known as microplastics (MPs), move through the air. We focus on their journey in a wind tunnel to mimic atmospheric transport. Depending on the air speed and the height of their release, they move downwards or upwards. These results suggest that MPs behave like mineral particles and that we can expect MPs to accumulate where natural dust also accumulates in the environment, offering insights for predicting the spread and impacts of MPs.
Our study explores how tiny plastic particles, known as microplastics (MPs), move through the...
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