Articles | Volume 2, issue 2
https://doi.org/10.5194/ar-2-225-2024
https://doi.org/10.5194/ar-2-225-2024
Research article
 | 
18 Jul 2024
Research article |  | 18 Jul 2024

Direct detection of polycyclic aromatic hydrocarbons on a molecular composition level in summertime ambient aerosol via proton transfer reaction mass spectrometry

Tobias Reinecke, Markus Leiminger, Andreas Klinger, and Markus Müller

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Cited articles

Agudelo-Castañeda, D. M., Teixeira, E. C., Schneider, I. L., Lara, S. R., and Silva, L. F. O.: Exposure to polycyclic aromatic hydrocarbons in atmospheric PM1.0 of urban environments: Carcinogenic and mutagenic respiratory health risk by age groups, Environ. Pollut., 224, 158–170, https://doi.org/10.1016/j.envpol.2017.01.075, 2017. 
Arndt, D., Wachsmuth, C., Buchholz, C., and Bentley, M.: A complex matrix characterization approach, applied to cigarette smoke, that integrates multiple analytical methods and compound identification strategies for non-targeted liquid chromatography with high-resolution mass spectrometry, Rapid Commun. Mass Spectrom., 34, e8571, https://doi.org/10.1002/rcm.8571, 2020. 
Borrás, E. and Tortajada-Genaro, L. A.: Characterisation of polycyclic aromatic hydrocarbons in atmospheric aerosols by gas chromatography-mass spectrometry, Anal. Chim. Acta, 583, 266–276, https://doi.org/10.1016/j.aca.2006.10.043, 2007. 
Bosque, R. and Sales, J.: Polarizabilities of Solvents from the Chemical Composition, J. Chem. Inf. Comput. Sci., 42, 1154–1163, https://doi.org/10.1021/ci025528x, 2002. 
Boutsidis, C. and Gallopoulos, E.: SVD based initialization: A head start for nonnegative matrix factorization, Pattern Recognition, 41, 1350–1362, https://doi.org/10.1016/j.patcog.2007.09.010, 2008. 
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Short summary
Condensed particulate polycyclic aromatic hydrocarbons (PAHs) are toxic compounds that may be detrimental to human health, even at low (sub-ng m-3) long-term exposure levels. The CHARON FUSION PTR-TOF 10k is capable of directly detecting PAHs on a chemical composition level at significantly lower mass concentrations. Herein, we report the time series of nine PAHs and identify three associated major sources and physicochemical processes for summertime aerosol in Innsbruck, Austria.
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